Heterocyclic compounds. Volume II. Five and six-members polycyclic compounds containing one o and s atom
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چکیده
منابع مشابه
Preparation and Reactions of Heterocyclic Compounds II
Commercial preparation of furan proceeds by way of the aldehyde, furfural, which in turn is generated from pentose containing raw materials like corncobs, as shown in the uppermost equation below. Similar preparations of pyrrole and thiophene are depicted in the second row equations. Equation 1 in the third row illustrates a general preparation of substituted furans, pyrroles and thiophenes fro...
متن کاملSynthesis, reactions and biological activity of some new bis-heterocyclic ring compounds containing sulphur atom
BACKGROUND The derivatives of thieno[2,3-b]thiophene belong to a significant category of heterocyclic compounds, which have shown a wide spectrum of medical and industrial application. RESULTS A new building block with two electrophilic center of thieno[2,3-b]thiophene derivatives 2 has been reported by one-pot reaction of diketone derivative 1 with Br2/AcOH in excellent yield. A variety of h...
متن کاملSynthesis of oxygen-containing heterocyclic compounds based on the intramolecular O–H insertion and Wolff rearrangement of a-diazocarbonyl compounds
The addition products of Ti(IV)-enolate derived from b-keto a-diazo carbonyl compound to ketones or a,b-unsaturated compounds were subjected to Rh2(OAc)4-catalyzed and photo-induced diazo decomposition. The Rh2(OAc)4-catalyzed reaction afforded intramolecular O–H insertion products, while the photo-induced reaction gave Wolff rearrangement/intramolecular nucleophilic addition products. The tran...
متن کاملSynthesis and analysis of some bis-heterocyclic compounds containing sulphur.
A facile and convenient synthesis of a series of bisheterocycles 7a,b 10, 12 and 13a,b containing a thieno[2,3-b]thiophene base unit via the versatile, hitherto unreported 3-[3,4-dimethyl-5-(3-nitrilopropanoyl)thieno[2,3-b]thiophen-2-yl]-3-oxopropanenitrile (4) is described.
متن کاملA Mini Review: Biological Significances of Nitrogen Hetero Atom Containing Heterocyclic Compounds
Heterocycles have vital interest in the pharmaceuticals and agrochemicals. Synthetic chemistry provides wealth of heterocyclic systems. More than 90% of drugs contain heterocycles ring and the interface between chemistry and biology. Scientific insight, discovery and applications are taking place by heterocyclic compounds. This review article covers theactive heterocycles that have shown consid...
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ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 1953
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed030p324.2